Diamond

Diamond type classification, the 4Cs grading system, fancy colours, natural vs lab-grown identification, and diamond verification instruments.

species/diamond 4Cs grading lab-grown HPHT CVD

Introduction

Diamond is the hardest natural material and one of the most valued gemstones.
Its unique combination of hardness, brilliance, and dispersion makes it ideal
for jewellery, while its structure and formation provide fascinating scientific
study.

Understanding diamond requires knowledge of its type classification (based on
nitrogen content), the 4Cs grading system, fancy colour assessment, and methods
to distinguish natural from laboratory-grown stones.

Diamond Type Classification

Diamonds are classified into types based on nitrogen content and its arrangement
in the crystal lattice. Type affects colour, physical properties, and response
to treatments.

Type System Overview

Type Nitrogen Content Characteristics Frequency
Type Ia Aggregated nitrogen (A and B centres) Cape series yellow tint; most common ~98% of natural
Type IaA Paired nitrogen (A centres) Near-colourless to light yellow Common
Type IaB Clustered nitrogen (B centres) Less yellow; may show H3/H4 centres Less common
Type Ib Isolated nitrogen Intense yellow or brown ~0.1% natural; common synthetic
Type IIa No nitrogen Colourless or brown; often finest quality ~1-2% natural
Type IIb Boron (no nitrogen) Blue; electrically conductive Very rare

Type Significance

Understanding diamond type is important because:

  • Treatment response: Type IIa brown diamonds can be HPHT-treated to colourless
  • Colour origin: Type determines cause of colour
  • Value: Type IIa diamonds are often exceptional
  • Synthetic identification: Type Ib common in HPHT synthetics
  • Scientific interest: Type reveals formation conditions

Testing for Type

Diamond type is determined by:

  • Infrared spectroscopy: Nitrogen absorption patterns
  • UV-Vis absorption: Colour centres
  • Photoluminescence: Characteristic emissions

Standard gemmological tools cannot determine type; laboratory analysis is required.

The 4Cs for Diamond

The GIA 4Cs system (Colour, Clarity, Cut, Carat weight) is the universal standard
for diamond grading. Understanding this system is essential for any gemmologist.

Colour Grading

D-Z Colour Scale

The GIA colour scale grades diamonds from D (colourless) to Z (light yellow/brown):

  • D, E, F: Colourless (most valuable)
  • G, H, I, J: Near-colourless
  • K, L, M: Faint yellow
  • N, O, P, Q, R: Very light yellow
  • S, T, U, V, W, X, Y, Z: Light yellow

Beyond Z, stones enter the "fancy colour" category where yellow is desirable.

Colour Grading Conditions

Accurate colour grading requires:

  • Master stones: Comparison set of known grades
  • Standard lighting: D65 daylight equivalent
  • Neutral background: White or grey grading tray
  • Controlled viewing: Table-down, pavilion up
  • Multiple observations: Check from different angles

Colour Price Impact

Colour Range Price Impact Notes
D-F Premium Colourless; highest value
G-H Good value Face-up appear colourless
I-J Budget friendly Slight warmth; good value
K+ Discounted Visible tint; value option

Clarity Grading

GIA Clarity Scale

Grade Name Description
FL Flawless No inclusions/blemishes at 10×
IF Internally Flawless No inclusions; minor blemishes at 10×
VVS1, VVS2 Very Very Slightly Included Minute inclusions; very difficult to see at 10×
VS1, VS2 Very Slightly Included Minor inclusions; difficult to see at 10×
SI1, SI2 Slightly Included Noticeable inclusions at 10×; may be eye-visible
I1, I2, I3 Included Obvious inclusions; may affect durability/beauty

Clarity Factors

Five factors determine clarity grade:

  1. Size: Larger inclusions have more impact
  2. Number: Multiple inclusions reduce grade
  3. Position: Central inclusions more visible
  4. Nature: Type of inclusion (feather vs crystal)
  5. Relief: Contrast with surrounding diamond

Eye-Clean Concept

Many buyers seek "eye-clean" diamonds:

  • No inclusions visible to unaided eye
  • Typically SI1 and above
  • Depends on stone size (larger = more visible)
  • Personal perception varies

Cut Grading

GIA Cut Grade (Round Brilliant)

GIA grades round brilliant cut on five levels:

  • Excellent: Maximum brilliance and fire
  • Very Good: High performance
  • Good: Standard appearance
  • Fair: Below standard
  • Poor: Significant performance issues

Cut Quality Factors

Factor Excellent Range Effect
Table % 54-57% Balance of brilliance and fire
Depth % 59-62.3% Light return and face-up size
Crown angle 34-35° Fire and brilliance balance
Pavilion angle 40.6-41° Critical for light return
Girdle Thin to slightly thick Durability and face-up size

Light Performance

Well-cut diamonds maximise:

  • Brilliance: White light return
  • Fire: Spectral dispersion
  • Scintillation: Sparkle pattern when moved

Poor cuts show:

  • Windowing: Light passes through
  • Extinction: Dark areas
  • Fish-eye: Girdle reflection visible

Carat Weight

Carat is the metric unit for gemstone weight: 1 carat = 0.200 grams = 200 milligrams.

Weight-Size Relationship

Standard round brilliant approximate dimensions by weight:

  • 0.25 ct: ~4.1mm diameter
  • 0.50 ct: ~5.1mm diameter
  • 1.00 ct: ~6.5mm diameter
  • 2.00 ct: ~8.2mm diameter

Actual dimensions vary based on cut proportions.

Price Per Carat Jumps

Price per carat increases at threshold weights:

  • 0.30, 0.40, 0.50, 0.70, 0.90 ct: Minor jumps
  • 1.00 ct: Major threshold (20-40% jump)
  • 1.50, 2.00, 3.00 ct: Significant premiums
  • 5.00+ ct: Exceptional premiums

A 0.99 ct diamond costs significantly less per carat than a 1.01 ct stone.

Fancy Colour Diamonds

Diamonds with colour beyond Z, or with colours other than yellow/brown, are graded
as fancy colours with different criteria.

Fancy Colour Grading

Grade Description
Faint Very light colour presence
Very Light Light colour visible
Light Easily seen colour
Fancy Light Entry to fancy grades
Fancy Moderate saturation
Fancy Intense Strong saturation
Fancy Vivid Maximum saturation (most valuable)
Fancy Deep Dark tone; saturation varies
Fancy Dark Very dark tone

Colour Causes

Colour Cause Rarity
Yellow Nitrogen (isolated) Common fancy colour
Brown Plastic deformation Most common
Blue Boron Very rare
Green Radiation exposure Rare
Pink/Red Plastic deformation Very rare; most valuable
Orange Nitrogen + deformation Rare
Black Graphite inclusions Relatively common
White Milky inclusions Uncommon

Value Hierarchy

Fancy colour value (generally, for equivalent saturation):

  1. Red: Rarest and most valuable
  2. Blue: Very rare; high value
  3. Pink: Extremely desirable
  4. Green: Rare; valuable
  5. Orange: Relatively rare
  6. Yellow: Most common fancy; value varies
  7. Brown: Most abundant; lowest fancy value

Natural vs Lab-Grown Diamonds

Distinguishing natural from laboratory-grown diamonds is increasingly important
as lab-grown quality and availability increase.

HPHT Diamond Characteristics

High Pressure High Temperature synthetics show:

  • Metallic inclusions: Iron/nickel flux catalyst
  • Colour zoning: May show cross-shaped zones
  • Fluorescence patterns: Different from natural
  • Magnetic: Metal inclusions attracted to magnet
  • Type: Often Type Ib (isolated nitrogen)

CVD Diamond Characteristics

Chemical Vapour Deposition synthetics show:

  • Striated growth: Parallel growth lines
  • Brown tint: Often HPHT post-treated
  • Unusual fluorescence: Orange or other colours
  • Very clean: Few inclusions typically
  • Type: Usually Type IIa

Detection Methods

Method Detects Limitation
DiamondView Growth patterns, fluorescence Expensive equipment
Photoluminescence Defect centres Laboratory required
UV-Vis absorption Colour centres Laboratory required
Infrared spectroscopy Nitrogen type Laboratory required
Magnetic testing HPHT metal inclusions Not all HPHT magnetic

Diamond Verification Instruments

Screening Devices

Various instruments help identify potential synthetics or simulants:

  • Thermal probes: Distinguish diamond from most simulants
  • Combined thermal/electrical: Separate diamond from moissanite
  • Type screening devices: Identify stones needing further testing
  • UV screening devices: Detect unusual fluorescence patterns

Laboratory Instruments

Instrument Purpose
DiamondView Fluorescence imaging of growth structures
FTIR spectrometer Diamond type and treatment detection
UV-Vis-NIR spectrometer Colour origin analysis
PL spectrometer Defect centre identification
Raman spectrometer Material verification

When to Test

Consider laboratory testing for:

  • Large, high-value diamonds
  • Unusually clean stones
  • Unusual fluorescence
  • Stones without documentation
  • Type II diamonds (more likely treated or synthetic)
  • Any stone with atypical features

Famous Diamonds